2-(4-Fluorophenyl)-3-methylsulfanyl-5-phenyl-1-benzofuran
نویسندگان
چکیده
In the title compound, C(21)H(15)FOS, the 4-fluoro-phenyl ring is rotated out of the benzofuran plane, making a dihedral angle of 24.3 (1)°. The dihedral angle between the phenyl ring and the benzofuran plane is 28.3 (1)°. The crystal structure may be stabilized by two very weak aromatic π-π inter-actions between the furan and the benzene rings of neighbouring benzofuran systems; the centroid-centroid distances are 3.909 (4) and 4.028 (4) Å.
منابع مشابه
2-(3-Fluorophenyl)-3-methylsulfanyl-5-phenyl-1-benzofuran
In the title compound, C(21)H(15)FOS, the dihedral angles between the mean plane of the benzofuran fragment and the pendant 3-fluoro-phenyl and phenyl rings are 1.76 (5) and 32.29 (5)°, respectively. In the crystal, mol-ecules are linked by a slipped π-π inter-action between the furan and benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.665 (2) Å, inter-planar distance =...
متن کامل5-(4-Fluorophenyl)-3-methylsulfanyl-2-phenyl-1-benzofuran
In the title compound, C(21)H(15)FOS, the dihedral angle between the mean plane of the benzofuran fragment and the mean planes of the pendant 4-fluoro-benzene and phenyl rings are 31.72 (6)° and 32.51 (6)°, respectively. In the crystal, the mol-ecules are linked by weak C-H⋯π inter-actions. The crystal studied was a merohedral twin with a 0.62 (9):0.38 (9) domain ratio.
متن کامل2,5-Bis(4-fluorophenyl)-2-methylsulfanyl-1-benzofuran
The crystal studied of the title compound, C(21)H(14)F(2)OS, was an inversion twin with a 0.67 (8):0.33 (8) domain ratio. The 4-fluoro-phenyl ring in the 2-position makes a dihedral angle of 25.14 (6)° with the mean plane of the benzofuran fragment, and the dihedral angle between 4-fluoro-phenyl ring in the 5-position and the mean plane of the benzofuran fragment is 28.50 (7)°. In the crystal, ...
متن کامل2-(4-Chlorophenyl)-3-methylsulfanyl-5-phenyl-1-benzofuran
In the title compound, C(21)H(15)ClOS, the 4-chloro-phenyl ring is rotated out of the benzofuran plane, making a dihedral angle of 21.50 (6)°. The dihedral angle between the 5-phenyl ring and the benzofuran plane is 29.39 (6)°. The crystal studied was an inversion twin with a 0.65 (7):0.35 (6) domain ratio.
متن کامل5-Chloro-2-(4-fluorophenyl)-3-phenylsulfinyl-1-benzofuran
In the title compound, C(20)H(12)ClFO(2)S, the O atom and the phenyl ring of the phenyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment; the phenyl ring is almost perpendicular to this plane [82.44 (5)°]. The 4-fluoro-phenyl ring is rotated out of the benzofuran plane, making a dihedral angle of 20.83 (6)°.
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